ChemicalBook > CAS DataBase List > ethyl 4,4,4-trifluorobut-2-enoate
ethyl 4,4,4-trifluorobut-2-enoate
- Product Name
- ethyl 4,4,4-trifluorobut-2-enoate
- CAS No.
- 406-10-0
- Chemical Name
- ethyl 4,4,4-trifluorobut-2-enoate
- Synonyms
- ethyl 4,4,4-trifluorobut-2-enoate;4,4,4-trifluoro-2-Butenoic acid ethyl ester;2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester
- CBNumber
- CB41551282
- Molecular Formula
- C6H7F3O2
- Formula Weight
- 168.11
- MOL File
- 406-10-0.mol
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ethyl 4,4,4-trifluorobut-2-enoate Property
- Density
- 1.125 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.3601(lit.)
- Flash point:
- 26°C
- Boiling point:
- 114-115°C(lit.)
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Safety
- RIDADR
- UN 3272 3 / PGIII
- WGK Germany
- 3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 269697
- Product name
- Ethyl 4,4,4-trifluorocrotonate
- Purity
- 98%
- Packaging
- 5g
- Price
- $77.2
- Updated
- 2024/03/01
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ethyl 4,4,4-trifluorobut-2-enoate Chemical Properties,Usage,Production
Uses
Ethyl 4,4,4-trifluorocrotonate was used in the synthesis of (2S,3S)-3-methyl- and (2S,3S)-3-trifluoromethylpyroglutamic acid. It undergoes diastereoselective Michael addition reaction with ethyl crotonate.
General Description
The Michael reaction between ethyl 4,4,4-trifluorocrotonate and a Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone was studied.
ethyl 4,4,4-trifluorobut-2-enoate Preparation Products And Raw materials
Raw materials
Preparation Products
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